What is the basicity of H3PO4?
The structure of H3PO4 is tetrahedral. It has three P—OH and one P = O bond as
Shown below:
Since it has three ionizable P—OH bonds, therefore, H3PO4 is tribasic as shown below:


Since it is tribasic, it forms three series of salts with NaOH, viz., NaH2PO4, Na2HPO4 and Na3PO4.