Predict reaction of 1N sulphuric acid with the following metals:
(i) Copper
E°(Cu2+/Cu) = +0.34 V
(ii) Lead
E°(Pb2+/Pb) = −0.13 V
(iii) Iron
E°(Fe2+/Fe) = −0.44 V
(i) Since E°(Cu2+/Cu) = +0.34 V is higher than E°(H+/H2) = 0.0 V, therefore copper will not react with 1N H2SO4 to produce H2 gas.
(ii) Since E°(Pb2+/Pb) = −0.13 V and E°(H+/H2) = 0.0 V, therefore lead will react with 1N H2SO4 to produce H2 gas.
(iii) Since E°(Fe2+/Fe) = −0.44 V and E°(H+/H2) = 0.0 V, therefore iron will react with 1N H2SO4 to produce H2 gas.