Question
Class 11ChemistryRedox Reactions

Can a solution of 1M ZnSO4 be stored in a vessel made of copper?
Given:
E°(Zn2+/Zn) = +0.76 V
E°(Cu2+/Cu) = +0.34 V

Verified Answer

Since E°(Zn2+/Zn) = −E°(Zn/Zn2+) = 0.76 V is at a lower potential than E°(Cu2+/Cu) = 0.34 V, therefore Zn can only lose electrons to Cu2+ ions. Conversely, Zn2+ cannot accept electrons from Cu and hence the following reaction will not occur:

Zn2+ + Cu ⟶ Zn + Cu2+

In other words, ZnSO4 solution can be safely stored in a copper vessel.