Calculate the oxidation number of
(i) S in H2S
(ii) C in CO2
(iii) C in CH2Cl2
(iv) N is (NH4)2SO4
(v) Pb in Pb3O4
(vi) P in Na3PO4
(i) S in H2S
Let oxidation number of S = x.
2(+1) + x = 0 ⟶ x = −2
Oxidation number of S = −2
(ii) C in CO2
Let oxidation number of C = x.
x + 2(−2) = 0 ⟶ x = +4
Oxidation number of C = +4
(iii) C in CH2Cl2
Let oxidation number of C = x.
x + 2(+1) + 2(−1) = x = 0
Oxidation number of C = 0
(iv) N in (NH4)2SO4
Let oxidation number of N = x.
2x + 8(+1) + (−2) = 2x + 6 = 0 ⟶ x = −3
Oxidation number of N = −3
(v) Pb in Pb3O4
Let oxidation number of Pb = x.
3x + 4(−2) = 0 ⟶ 3x − 8 = 0 ⟶ x = 8/3
Oxidation number of Pb = 8/3
(vi) P in Na3PO4
Let oxidation number of P = x.
3(+1) + x + 4(−2) = x − 5 = 0 ⟶ x = +5
Oxidation number of P = +5