Question
Class 11ChemistryThermodynamics

Calculate the enthalpy of formation of carbon monoxide (CO) from the following data:

(i)   C(s) + O2(g) → CO2(g); ΔrH° = −393.5 kJ mol−1

(ii)  CO(g) + 1/2O2(g) → CO2(g); ΔrH° = −283.0 kJ mol−1

Verified Answer

We aim at : C(s) +1/2O2(g) → CO(g); ΔfH° = ?

Subtracting equation (ii) from equation (i), we get

C(s) + 1/2 O2(g) − CO(g) → 0; ΔrH° = −393.5 − (−283.0) = −110.5 kJ mol−1

C(s) +1/2O2(g) → CO(g); ΔrH° = −110.5 kJ