Question
Class 11ChemistryThermodynamics

A swimmer coming out from a pool is covered with a film of water weighing about 18 g. How much heat must be supplied to evaporate this water at 298 K? Calculate the internal energy  of vaporization at 100°C. ∆vapH° for water at 373 K = 40.66 kJ mol–1.   

Verified Answer

The process of evaporation is: 18g H2O(l) → 18g H2O(g)

Number of moles in 18g H2O =18g/18g mol−1= 1 mol

Δng = 1 − 0 = 1 mol

∴  Δvap U° = ΔvapH° − ΔngRT = 40.66 kJ mol−1 − (1 mol)(8.314 × 10−3 kJ K−1 mol−1)(298 K)

= 40.66 kJ mol−1 − 3.10 kJ mol−1 = 37.56 kJ mol−1