One mole diatomic gas at 1.23 ATM is compressed adiabatically from 40L to 20L. What is the new pressure and new temperature?
For an adiabatic process, we use the relations:
For a diatomic gas, γ (gamma) = 7/5 = 1.4
P₂ = P₁ × (V₁ / V₂)^γ
P₂ = 1.23 × (40 / 20)^1.4
P₂ = 1.23 × (2)^1.4
2^1.4 ≈ 2.64
P₂ ≈ 1.23 × 2.64 ≈ 3.25 atm
T₂ / T₁ = (V₁ / V₂)^(γ−1)
T₂ / T₁ = (2)^(0.4)
2^0.4 ≈ 1.32
So,
T₂ ≈ 1.32 × T₁
In adiabatic compression, pressure and temperature both increase, and γ (heat capacity ratio) plays a crucial role.