Question
GeneralGeneralGeneral

A dibromo compound C9H10Br2 reacts with sodamide followed by dilute HCl and later with mercuric sulphate and sulphuric acid. Final product gives positive iodoform test and negative Tollens test. Identify compound P.

Verified Answer

Solution:

Dibromo compound on treatment with sodamide forms an alkyne.

Hydration of alkyne using HgSO4/H2SO4 gives ketone.

Positive iodoform test indicates presence of CH3CO− group.

Negative Tollens test confirms compound is not an aldehyde.

Hence final compound is methyl ketone:

C6H5COCH3

Answer: Acetophenone (1-Phenylethanone)